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Highly oxygenated meroterpenoids from the Antarctic fungus Aspergillus terreus

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单位： [1]Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Hubei, Peoples R China [2]Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China [3]Huazhong Univ Sci & Technol, Tongji Hosp, Tongji Med Coll, Dept Pharm, Wuhan 430030, Hubei, Peoples R China [4]Huazhong Univ Sci & Technol, Cent Hosp Wuhan, Dept Pharm, Tongji Med Coll, Wuhan 430030, Hubei, Peoples R China

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关键词： Aspergillus terreus (Trichocomaceae) Antarctic fungus Terreustoxins Immunosuppressive activity

摘要：

Eleven highly oxygenated meroterpenoids, named terreustoxins A - K, along with five known analogues, were isolated from the Antarctic fungus Aspergillus terreus. The structures and absolute configurations of these un-described compounds were characterized by NMR spectroscopy, single-crystal X-ray crystallography, and ECD experiments. Terreustoxins A - D are the first examples of meroterpenoids with two ortho-hydroxy groups at C-6 and C-7 in the terretonins family. Terreustoxin C and terretonin inhibited the proliferation of Con A-induced murine T cells at the concentration of 10 mu M.

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出版当年[2018]版：

大类 | 3 区生物

小类 | 2 区植物科学 3 区生化与分子生物学

最新[2025]版：

大类 | 2 区生物学

小类 | 2 区生化与分子生物学 2 区植物科学

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出版当年[2017]版：

Q1 PLANT SCIENCES Q2 BIOCHEMISTRY & MOLECULAR BIOLOGY

最新[2023]版：

Q2 BIOCHEMISTRY & MOLECULAR BIOLOGY Q2 PLANT SCIENCES

影响因子： 3.2 最新[2023版] 3.4 最新五年平均 3.186 出版当年[2017版] 3.041 出版当年五年平均 3.205 出版前一年[2016版] 2.905 出版后一年[2018版]

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第一作者单位： [1]Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Hubei, Peoples R China

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