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Colletotrichumine A, a novel indole-pyrazine alkaloid with an unprecedented C16N3-type skeleton from cultures of Colletotrichum capsici

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单位: [1]Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Peoples R China [2]Huazhong Univ Sci & Technol, Tongji Hosp, Tongji Med Coll, Wuhan 430030, Peoples R China
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关键词: Fungi Colletotrichum capsici Indole-pyrazine alkaloid X-ray diffraction analysis

摘要:
Chemical investigations on the EtOAc extract of the cultures of Colletotrichum capsici afforded a novel indole-pyrazine alkaloid embodying a structurally unique C16N3-type skeleton, colletotrichumine A (1), together with five known steroids (2-6). Their structures were elucidated by spectroscopic analysis and that of 1 was further confirmed by a single-crystal X-ray diffraction method. The plausible biogenetic pathway of 1 was also discussed. (C) 2014 Elsevier Ltd. All rights reserved.

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出版当年[2013]版:
大类 | 3 区 化学
小类 | 3 区 有机化学
最新[2025]版:
大类 | 4 区 化学
小类 | 4 区 有机化学
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Q2 CHEMISTRY, ORGANIC
最新[2023]版:
Q3 CHEMISTRY, ORGANIC

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第一作者单位: [1]Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Peoples R China
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