Chemical investigations on the EtOAc extract of the cultures of Colletotrichum capsici afforded a novel indole-pyrazine alkaloid embodying a structurally unique C16N3-type skeleton, colletotrichumine A (1), together with five known steroids (2-6). Their structures were elucidated by spectroscopic analysis and that of 1 was further confirmed by a single-crystal X-ray diffraction method. The plausible biogenetic pathway of 1 was also discussed. (C) 2014 Elsevier Ltd. All rights reserved.
基金:
Program for New Century Excellent Talents in University, State Education Ministry of China [NCET-2008-0224]; Fundamental Research Funds for the Central Universities of China [HUST0118-5140048]; National Natural Science Foundation of China [31270395]
第一作者单位:[1]Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Peoples R China
通讯作者:
推荐引用方式(GB/T 7714):
Hu Zhengxi,Wang Jianping,Bi Xiaobin,et al.Colletotrichumine A, a novel indole-pyrazine alkaloid with an unprecedented C16N3-type skeleton from cultures of Colletotrichum capsici[J].TETRAHEDRON LETTERS.2014,55(44):6093-6095.doi:10.1016/j.tetlet.2014.09.041.
APA:
Hu, Zhengxi,Wang, Jianping,Bi, Xiaobin,Zhang, Jinwen,Xue, Yongbo...&Zhang, Yonghui.(2014).Colletotrichumine A, a novel indole-pyrazine alkaloid with an unprecedented C16N3-type skeleton from cultures of Colletotrichum capsici.TETRAHEDRON LETTERS,55,(44)
MLA:
Hu, Zhengxi,et al."Colletotrichumine A, a novel indole-pyrazine alkaloid with an unprecedented C16N3-type skeleton from cultures of Colletotrichum capsici".TETRAHEDRON LETTERS 55..44(2014):6093-6095