Hyperhexanones A (1) and B (2), two novel polycyclic polyprenylated acylphloroglucinol (PPAPs) derivatives, were isolated from Hypericum sampsonii. Compound 1 possesses a novel 1,2-seco-bicyclo[3.3.1]-PPAP skeleton, which represents a crucial intermediate from bicydo[3.3.1]-PPAPs to the peculiar cyclohexanone monocyclic-PPAPs (CM-PPAPs). A plausible biogenetic pathway was proposed to discuss the origins of the CM-PPAPs. (C) 2016 The Authors. Published by Elsevier Ltd.
基金：
Program for New Century Excellent Talents in University, State Education Ministry of China [NCET-2008-0224]; National Natural Science Foundation of China [31370372, 21502057, 81573316]; National Science and Technology Project of China [2011ZX09102-004]; China Postdoctoral Science Foundation [2015M572154]; Fundamental Research Fund for the Central Universities [2016YXMS149]
第一作者单位：[1]Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Hangkong Rd 13, Wuhan 430030, Peoples R China
通讯作者：
推荐引用方式(GB/T 7714)：
Zhu Hucheng,Chen Chunmei,Yang Jing,et al.Hyperhexanone A, a crucial intermediate from bicyclo[3.3.1]- to cyclohexanone monocyclic-polycyclic polyprenylated acylphloroglucinols[J].TETRAHEDRON.2016,72(31):4655-4659.doi:10.1016/j.tet.2016.06.035.
APA：
Zhu, Hucheng,Chen, Chunmei,Yang, Jing,Li, Dongyan,Zhang, Jinwen...&Zhang, Yonghui.(2016).Hyperhexanone A, a crucial intermediate from bicyclo[3.3.1]- to cyclohexanone monocyclic-polycyclic polyprenylated acylphloroglucinols.TETRAHEDRON,72,(31)
MLA：
Zhu, Hucheng,et al."Hyperhexanone A, a crucial intermediate from bicyclo[3.3.1]- to cyclohexanone monocyclic-polycyclic polyprenylated acylphloroglucinols".TETRAHEDRON 72..31(2016):4655-4659
